В адрес руководства Института химии СПбГУ поступила благодарность П.М. Толстому за проведение семинара о достижениях физической химии с учениками старших классов школы №20 Санкт-Петербурга.
Archive for 29.03.2018
29
Мар 2018
Благодарность
A. Grevtsev |
Комментарии к записи Благодарность отключены
22
Мар 2018
J. Polym. Sci. A, 2018, 387-398
V.A. Rozentsvet, O.A. Stotskaya, V.P. Ivanova, M.G. Kuznetsova, P.M. Tolstoy, S.V. Kostjuk
“Structural characterization of polybutadiene synthesized via cationic mechanism”
J. Polym. Sci. A, 2018, 56, 387-398
DOI: 10.1002/pola.28905
The microstructure of polybutadiene synthesized via cationic polymerization using TiCl4‐based initiating systems has been investigated using 1D (1Н, 2Н, and 13С) and 2D (HSQC and HMBC) NMR spectroscopy. It was found that trans‐1,4‐unit is predominant structure of unsaturated part of polymer chain. Besides, the small amount of 1,2‐structures was also detected, while cis‐1,4‐units were totally absent. The signals of carbon atoms of three types of head groups (trans‐1,4‐, 1,2‐, and tert‐butyl) and two types of end groups (trans‐1,4‐Cl and 1,2‐Cl) were identified for the first time in macromolecules of cationic polybutadiene. It was showed that tert‐butyl head groups were formed due to the presence in monomer of admixtures of isobutylene. The new methodology for calculation of the content of different structural units in polybutadiene chain as well as the head and end groups was proposed. It was established that main part of 1,2‐units distributed randomly along the polybutadiene chain as separate units between trans‐1,4‐structures.
22
Мар 2018
FIRST
П.М. Толстой провел занятие на тему «ЯМР систем с водородной связью» для студентов бакалавриата и магистратуры университета Ювяскюля (Финляндия) в рамках русско-финского студенческого семинара по программе обмена FIRST. Программа мероприятий в Институте химии СПбГУ.
19
Мар 2018
Турнир школьников
Ресурсный центр МРМИ посетили участники Всероссийского химического турнира школьников. П.М. Толстой провел демонстрацию оборудования и рассказал нашим гостям о возможностях современных магнитно-резонансных методов исследования, реализованных в рц.
16
Мар 2018
New Journal of Chemistry, 2017, 41, 13918-13928
A.A. Vereschagin, V.V. Sizov, P.S. Vlasov, E.V. Alekseeva, A.S. Konev, O.V. Levin
“Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand”
New Journal of Chemistry, 2017, 41, 13918-13928
DOI: 10.1039/c7nj03526h
A novel electrode material was prepared by electrochemical oxidation of [4,4′-phenylazo-2,2′-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(II)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main components of the material and the nature of the linkage between them. The morphology of the material films was explored by SEM analysis. The electrochemical properties of the new material were studied by a set of voltammetric methods and an unusual stability of the material in aqueous medium was observed.
A. Grevtsev |
Комментарии к записи New Journal of Chemistry, 2017, 41, 13918-13928 отключены
12
Мар 2018
Tetrahedron, 2017, 73, 671-680
M.M. Efremova, R.R. Kostikov, A.V. Stepakov, T.L. Panikorovsky, V.S. Shcherbakova, A.V. Ivanov, A.P. Molchanov
“Unusual Lewis-acid catalyzed formal (3+3)-cycloaddition of azomethine imines and nitrones to N-vinylpyrroles”
Tetrahedron, 2017, 73, 671-680
DOI: 10.1016/j.tet.2016.12.034
The addition of Lewis acids change the reaction mechanism of the cycloaddition of N-vinylpyrroles with azomethine imine and C,N-diarylnitrones. The formal (3+3)-cycloaddition is observed instead of (3+2)-dipolar cycloaddition, which take place in the absence of catalysts. This unusual (3+3)-cycloaddition leads to heterocyclic compounds with pyrazolo[1,2-a]pyrrolo[1,2-d][1,2,4]triazine- and pyrrolo[2,1-d][1,2,5]oxadiazine cores, which are difficultly achievable by other methods.
A. Grevtsev |
Комментарии к записи Tetrahedron, 2017, 73, 671-680 отключены
06
Мар 2018
Mendeleev Commun., 2017, 27, 95-96
G. P. Kantin, M. Yu. Krasavin
“Microwave-promoted reaction of N-alk-1-enyl chloroacetamides with sodium azide unexpectedly yields 1H-imidazol-5(4H)-ones”
Mendeleev Commun., 2017, 27, 95-96
DOI: 10.1016/j.mencom.2017.01.031
A novel method to prepare biologically relevant 1H-imidazol-5(4H)-ones from aliphatic amines, isobutyraldehyde, chloroacetyl chloride and sodium azide under microwave irradiation has been developed.
A. Grevtsev |
Комментарии к записи Mendeleev Commun., 2017, 27, 95-96 отключены
05
Мар 2018
Февраль
В Феврале выполнено 2014 заявок на сервисные измерения.
Измерено:
- 1848 спектр 1H
- 366 спектра 13C
- 87 спектров DEPT
- 41 спектров COSY
- 22 спектра NOESY
- 85 спектра 31Р
- 91 спектров 19F
Выполнено 239 заявок на исследовательскую работу.
A. Grevtsev |
Комментарии к записи Февраль отключены