P. Schah-Mohammedi, I.G. Shenderovich, C. Detering, H.-H. Limbach, P.M. Tolstoy, S.N. Smirnov, G.S. Denisov, N.S. Golubev, “Hydrogen/Deuterium Isotope Effects on NMR Chemical Shifts of Formally Symmetric Complexes with a Strong Intermolecular Hydrogen Bond in Liquid Solutions at 100-150K”, J. Am. Chem. Soc., 2000, 122, 12878-12879.
C. Detering, P.M. Tolstoy, N.S.Golubev, G.S. Denisov, H.-H. Limbach, “Vicinal H/D Isotope Effects in NMR Spectra of Complexes with Coupled Hydrogen Bonds. Phosphoric Acids”, Doklady Phys. Chem., 2001, 379, 1-4.
I.G. Shenderovich, H.-H. Limbach, S.N. Smirnov, P.M. Tolstoy, G.S. Denisov, N.S. Golubev, “H/D Isotope Effects on the Low-Temperature NMR Parameters and Hydrogen Bond Geometries of (FH)2F– and (FH)3F– dissolved in CDF3/CDF2Cl”, Phys. Chem. Chem. Phys., 2002, 4(22), 5488-5497.
I.G. Shenderovich, P.M. Tolstoy, N.S.Golubev, S.N. Smirnov, G.S. Denisov, H.-H. Limbach, “Low-Temperature NMR Studies of the Structure and Dynamics of a Novel Series of Acid-Base Complexes of HF with Collidine Exhibiting Scalar Couplings Across Hydrogen Bonds”, J. Am. Chem. Soc., 2003, 125, 11710-11720.
N.S. Golubev, S.M. Melikova, D.N. Shchepkin, I.G. Shenderovich, P.M. Tolstoy, G.S. Denisov, “Interpretation of Hydrogen/Deuterium Isotope Effects on NMR Chemical Shifts of [FHF]- Ion Based on Calculations of Nuclear Magnetic Shielding Tensor Surface”, Z. Phys. Chem., 2003, 217, 1549-1563.
N. Pérez-Hernández, C. Pérez, M.L. Rodríguez, C. Foces-Foces, P.M. Tolstoy, H.-H. Limbach, E.Q. Morales, R. Pérez, J.D. Martín, “Water Molecules in Hydroxy/Acid Networks as a Competition between Dynamics and Bonding. Synthesis of a Wet Hydrophobic Pore”, Bioorg. Med. Chem., 2004, 12, 1305-1314.
P.M. Tolstoy, P. Schah-Mohammedi, S.N. Smirnov, N.S.Golubev, G.S. Denisov, H.-H. Limbach, „Characterization of Fluxional Hydrogen-Bonded Complexes of Acetic Acid and Acetate by NMR: Geometries and Isotope and Solvent Effects”, J. Am. Chem. Soc., 2004, 126, 5621-5634.
N.S. Golubev, I.G. Shenderovich, P.M. Tolstoy, D.N. Shchepkin, “Solvent induced temperature dependencies of NMR parameters of hydrogen bonded anionic clusters”, J. Mol. Struct., 2004, 697, 9-15.
N.S. Golubev, P.M. Tolstoy, S.N. Smirnov, G.S. Denisov, H.-H. Limbach, „Low-temperature NMR spectra of fluoride–acetic acid hydrogen-bonded complexes in aprotic polar environment”, J. Mol. Struct., 2004, 700, 3-12.
P.M. Tolstoy, S.N. Smirnov, I.G. Shenderovich, N.S.Golubev, G.S. Denisov, H.-H. Limbach, “NMR studies of solid state—solvent and H/D isotope effects on hydrogen bond geometries of 1:1 complexes of collidine with carboxylic acids”, J. Mol. Struct., 2004, 700, 19-27.
H.-H. Limbach, M. Pietrzak, H. Benedict, P.M. Tolstoy, N.S. Golubev, G.S. Denisov, „Empirical corrections for anharmonic zero-point vibrations of hydrogen and deuterium in geometric hydrogen bond correlations“, J. Mol. Struct., 2004, 706, 115-119.
H.-H. Limbach, M. Pietrzak, S. Sharif, P.M. Tolstoy, I.G. Shenderovich, S.N. Smirnov, N.S. Golubev, G.S. Denisov, “NMR Parameters and Geometries of OHN and ODN Hydrogen Bonds of Pyridine-Acid Complexes”, Chem. Eur. J., 2004, 10, 5195-5204.
H. Zimmermann, P. Tolstoy, H.-H. Limbach, R. Poupko, Z. Luz, “The Saddle Form of Cyclotriveratrylene”, J. Phys. Chem. B, 2004, 108, 18772-18778.
S.F. Bureiko, N.S.Golubev, G.S. Denisov, S.Yu. Kucherov, P.M. Tolstoi, “3,5-Dimethylpyrazole Complexes with Strong Carboxylic Acids“, Russ. J. Gen. Chem., 2005, 75(11), 1821-1829.
N.S. Golubev, R.E. Asfin, S.N. Smirnov, P.M. Tolstoy, “Study of Hydrogen Bonding by Hypophosphorous Acid H2P(O)OH Using 1H, 2H, 31P and 15N NMR spectroscopy at Slow Exchange”, Russ. J. Gen. Chem., 2006, 76(6), 956-966. (in Russian)
D.V. Andreeva, B. Ip, A.A. Gurinov, P.M. Tolstoy, G.S. Denisov, I.G. Shenderovich, H.-H. Limbach, “Geometrical Features of Hydrogen Bonded Complexes Involving Sterically Hindered Pyridines”, J. Phys. Chem. A, 2006, 110, 10872-10879.
N.S. Golubev, P.M. Tolstoy, D.N. Schchepkin, “Estimation of contribution of electron-vibrational interaction to the H/D isotope effect of the shielding of the hydrogen bond bridging particle”, Russ. J. Gen. Chem., 2006, 76(8), 1233-1240 (in Russian).
S. Sharif, M. Huot, P.M. Tolstoy, M.D. Toney, K.H.M. Jonsson, H.-H. Limbach, “15N Nuclear Magnetic Resonance Studies of Acid-Base Properties of Pyridoxal-5′-Phosphate Aldimines in Aqueous Solution”, J. Phys. Chem. B, 2007; 111(15), 3869-3876.
S. Sharif, E. Fogle, M.D. Toney, G.S. Denisov, I.G. Shenderovich, G. Buntkowsky, P.M. Tolstoy, M. Chan Huot, H.-H. Limbach, “NMR Localization of Protons in Critical Enzyme Hydrogen Bonds”, J. Am. Chem. Soc., 2007, 129(31), 9558-9559.
N.S. Golubev, S.N. Smirnov, P.M. Tolstoy, S. Sharif, M.D. Toney, G.S. Denisov, H.-H. Limbach, “Observation by NMR of the tautomerism of an intramolecular OHOHN-charge relay chain in a model Schiff base”, J. Mol. Struct., 2007, 844, 319-327.
N.S. Golubev, G.S. Denisov, S. Macholl, S.N. Smirnov, I.G. Shenderovich, P.M. Tolstoy, „NMR Study of Blue-Shifting Hydrogen Bonds Formed by Fluoroform in Solution“, Z. Phys. Chem., 2008, 222, 1225-1245.
P.M. Tolstoy, B. Koeppe, G.S. Denisov, H.-H. Limbach, “Combined NMR/UV-Vis Spectroscopy in the LiquidState: Study of the Geometries of Strong OHO Hydrogen Bonds of Phenols with Carboxylic Acids”, Ang. Chem. Int. Ed.,2009, 48, 5745-5747.
H.-H. Limbach, P.M. Tolstoy, N. Perez-Hernandez, J. Guo, I.G. Shenderovich, G.S. Denisov,“OHO Hydrogen Bond Geometries and NMR Chemical Shifts: From Equilibrium Structures to Geometric H/D Isotope Effects with Applications for Water, Protonated Water and Compressed Ice”, Israel J. Chem.,2009, 49, 199-216.
N.S. Golubev, C.Detering, S.N. Smirnov, I.G. Shenderovich, G.S. Denisov, H.-H. Limbach, P.M. Tolstoy, “H/D Isotope Effects on NMR Chemical Shifts of Nuclei Involved in a Hydrogen Bridge of Hydrogen Iso-cyanide Complexes with Fluoride Anion”, Phys. Chem. Chem. Phys.,2009,11, 5154-5159.
M. Pietrzak, J.P. Wehling, S. Kong, P.M. Tolstoy, I.G. Shenderovich, C. Lopez, R.M. Claramunt, J. Elguero, G.S. Denisov, H.-H. Limbach, “Symmetrization of Cationic Hydrogen Bridges of Protonated Sponges Induced by Solvent and Counteranion Interactions as Revealed by NMR Spectroscopy”, Chem. Eur. J., 2010, 16, 1679-1690.
M. Chan-Huot, C. Niether, S. Sharif, P. M. Tolstoy, M. D. Toney, H.-H. Limbach “NMR Studies of the Protonation States of Pyridoxal 5’-phosphate in Water”, J. Mol. Struct. 2010, 976, 282-289.
L. Szyc, J. Guo, M. Yang, J. Dreyer, P.M. Tolstoy, E.T.J. Nibbering, B. Czarnik-Matusewicz, T. Elsaesser, H.-H. Limbach, “The Hydrogen-Bonded 2-Pyridone Dimer Model System. I. Combined NMR and FT-IR Study”, J. Phys. Chem. A2010, 114, 7749-7760.
S.B. Lesnichin, P.M. Tolstoy, H.H. Limbach, I.G. Shenderovich, “Counteranion-dependent mechanisms of intramolecular proton transfer in aprotic solution”, Physical Chemistry Chemical Physics, 2010, 12, 10373-10379.
P.M. Tolstoy, J. Guo, B. Koeppe, N.S. Golubev, G.S. Denisov, S.N. Smirnov, H.-H. Limbach, “Geometries and Tautomerism of OHN Hydrogen Bonds in Aprotic Solution Probed by H/D Isotope Effects on 13C NMR Chemical Shifts”, J. Phys. Chem. A2010, 114, 10775-10782.
M. Chan-Huot, S. Sharif, P.M. Tolstoy, M.D. Toney, H.-H. Limbach, “NMR Studies of the Stability, ProtonationStatesand Tautomerism of 13C and 15N Labeled Aldimines of the Coenzyme Pyridoxal 5’-phosphate in Water”, Biochemistry, 2010, 49, 10818-10830.
D. Ajami, P.M. Tolstoy, H. Dube, S. Odermatt, B. Koeppe, J. Guo, H.-H. Limbach, J. Rebek Jr., “Compressed Hydrogen Bonds Isolated in Encapsulation Complexes”, Angew. Chem. Int. Ed.2011, 50, 528-531.
J. Guo, B. Koeppe, P.M. Tolstoy, “Trimethylglycine Complexes with Carboxylic Acids and HF: Solvation by Polar Aprotic Solvent”, PCCP, 2011, 13, 2335-2341.
B. Koeppe, P.M. Tolstoy, E.T. J. Nibbering, T. Elsaesser, “Two-dimensional UV-vis/NMR Correlational Spectroscopy: A Heterospectral Signal Assignment of Hydrogen-Bonded Complexes”, J. Phys. Chem. Lett., 2011, 2, 1106-1110.
B. Koeppe, P.M. Tolstoy, H.-H. Limbach, “Reaction Pathways of Proton Transfer in Hydrogen bonded Phenol-Carboxylate Complexes explored by UVNMR”, J. Am. Chem. Soc., 2011, 133, 7897-7908.
J. Guo, P.M. Tolstoy, B. Koeppe, G.S. Denisov, H.-H. Limbach, “NMR Study of Conformational Exchange and Geometries of Intramolecular Hydrogen Bonds in Monoanions of Succinic Acid and Derivatives”, J. Phys. Chem. A, 2011, 115, 9828-9836.
H.-H. Limbach, M. Chan-Huot, S. Sharif, P.M. Tolstoy, I.G. Shenderovich, G.S. Denisov, M.D. Toney, “Critical hydrogen bonds and protonation states of pyridoxal 5’-phosphate revealed by NMR”, Biochimica Biophysica Acta Proteins and Proteomics, 2011, 1814, 1426-1437.
N.Yu. Gorobets, S.A. Yermolayev, T. Gurley, A.A. Gurinov, P.M. Tolstoy, I.G. Shenderovich, N.E. Leadbeater, “Difference between 1H NMR signals of primary amide protons as a simple spectral index of the amide intramolecular hydrogen bond strengths”, J. Phys. Org. Chem., 2012, 25, 287-295.
B.C.K. Ip, I.G. Shenderovich, P.M. Tolstoy, J. Frydel, G.S. Denisov, G. Buntkowsky, H.-H. Limbach, “NMR Studies of H/D Isotope and Phase Effects on 4-Methylpyridine-Pentachlorophenol Complexes and Implications for the Shapes of Hydrogen-bonded Protons in the Solid and the Liquid State”, J. Phys. Chem. A 2012, 116, 11370-11387.
J. Guo, P.M. Tolstoy, B. Koeppe, N.S. Golubev, G.S. Denisov, S.N. Smirnov, H.-H. Limbach, “Hydrogen Bond Geometries and Proton Tautomerism of Homo-Conjugated Anions of Carboxylic Acids Studied via H/D Isotope Effects on 13C NMR Chemical Shifts”, J. Phys. Chem. A2012, 116, 11180-11188.
G.A. Silantyev, O.A. Filippov, P.M. Tolstoy, N.V. Belkova, L.M. Epstein, K. Weisz, E.S. Shubina, „Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy”, Inorganic Chemistry2013, 52, 1787-1797.
B. Koeppe, J. Guo, P.M. Tolstoy, G.S. Denisov, H.-H. Limbach, “Solvent and H/D Isotope Effects on the Proton Transfer Pathways in Heteroconjugated Hydrogen-Bonded Phenol-Carboxylic Acid Anions Observed by Combined UV–vis and NMR Spectroscopy”, J. Am. Chem. Soc.2013, 135, 7553-7566.
Y. Rozhkova, A. A. Gurinov, P. M. Tolstoy, G. S. Denisov, I. G. Shenderovich, V. I. Korotkov, “Acridine – a Promising Fluorescence Probe of Non-Covalent Molecular Interactions”, Zeitschrift für Physikalische Chemie2013, 227, 857-868.
B. Koeppe, E.T.J. Nibbering, P.M. Tolstoy, “NMR and FT-IR studies on the association of derivatives of thymidine, adenosine, and 6-N-methyl-adenosine in aprotic solvents”, Zeitschrift für Physikalische Chemie2013, 227, 723-749.
M. Chan-Huot, A. Dos, R. Zander, S. Sharif, P.M. Tolstoy, S. Compton, E. Fogle, M.D. Toney, I.G. Shenderovich, G.S. Denisov, H.-H. Limbach, “NMR Studies of Protonation and Hydrogen Bond States of Internal Aldimines of Pyridoxal 5’-Phosphate Acid-Base in Alanine Racemase, Aspartate Aminotransferase, and Poly-L-lysine”, J. Am. Chem. Soc.2013, 135, 18160-18175.