Dalton Transactions, 2017, 46, 12425-12429

A.V. Artem’ev, I.Yu. Bagryanskaya, E.P. Doronina, P.M. Tolstoy, A.L. Gushchin, M.I. Rakhmanova, A.Yu. Ivanove, A.O. Suturina

“A new family of clusters containing a silver-centered tetracapped [Ag@Ag4(μ3-P)4] tetrahedron, inscribed within a N12 icosahedron”

Dalton Transactions, 2017, 46, 12425-12429.
DOI: 10.1039/C7DT02597A

source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT02597A#!divAbstract

An unprecedented silver-centered P-tetracapped [Ag@Ag4(μ3-P)4] tetrahedron inscribed within a N12 icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting AgI salts with tris(2-pyridyl)phosphine (Py3P).

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