A.V. Artem’ev, I.Yu. Bagryanskaya, E.P. Doronina, P.M. Tolstoy, A.L. Gushchin, M.I. Rakhmanova, A.Yu. Ivanove, A.O. Suturina
“A new family of clusters containing a silver-centered tetracapped [Ag@Ag4(μ3-P)4] tetrahedron, inscribed within a N12 icosahedron”
Dalton Transactions, 2017, 46, 12425-12429.
An unprecedented silver-centered P-tetracapped [Ag@Ag4(μ3-P)4] tetrahedron inscribed within a N12 icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting AgI salts with tris(2-pyridyl)phosphine (Py3P).